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Issue 43, 2009
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Self-assembly of star-shaped heteropoly-15-palladate(II)

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Abstract

A novel heteropolyoxopalladate structural type has been discovered: the polyoxo-15-palladate(II) [Pd0.4Na0.6⊂Pd15P10O50H6.6]12− (Pd15) has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD, elemental analysis, IR, TGA, 31P NMR and electrochemistry; preliminary catalytic studies showed that Pd15 is active as a catalyst in alcohol oxidation by dioxygen.

Graphical abstract: Self-assembly of star-shaped heteropoly-15-palladate(II)

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Publication details

The article was received on 16 Jun 2009, accepted on 24 Aug 2009 and first published on 02 Sep 2009


Article type: Communication
DOI: 10.1039/B917079K
Citation: Dalton Trans., 2009, 9385-9387
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    Self-assembly of star-shaped heteropoly-15-palladate(II)

    N. V. Izarova, R. N. Biboum, B. Keita, M. Mifsud, I. W. C. E. Arends, G. B. Jameson and U. Kortz, Dalton Trans., 2009, 9385
    DOI: 10.1039/B917079K

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