Issue 34, 2009

Synthesis of chiral large-ring triangular salen ligands and structural characterization of their complexes

Abstract

Large chiral triangular macrocycles having three salen ligand sites were obtained by cyclocondensation of trans-1,2-diaminocyclohexane with linearly connected bis-salicylaldehydes. Structures of the ligands and their titanium(IV) or zinc(II) complexes have been characterized by means of spectroscopic (CD) and computational (DFT) methods.

Graphical abstract: Synthesis of chiral large-ring triangular salen ligands and structural characterization of their complexes

Supplementary files

Article information

Article type
Paper
Submitted
12 May 2009
Accepted
27 May 2009
First published
02 Jul 2009

Dalton Trans., 2009, 6783-6789

Synthesis of chiral large-ring triangular salen ligands and structural characterization of their complexes

M. Kwit, B. Zabicka and J. Gawronski, Dalton Trans., 2009, 6783 DOI: 10.1039/B909445H

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