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Issue 35, 2009
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Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts

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Abstract

New PdBr2-bis(N-heterocyclic carbene) complexes derived from 4,7-dibutoxybenzimidazole and 5,6-dibutoxybenzimidazole have been synthesized and structurally and spectroscopically characterized. The complexes show much greater solubility compared to the parent complex derived from benzimidazole, and interesting structural characteristics dependent on the position of the butoxy substituents. The complexes display high activities in the coupling of aryl iodides in the Mizoroki–Heck reaction and moderate activities in the Suzuki–Miyaura coupling of inactivated aryl bromides at low catalyst loadings, although activity differences between pre-catalysts has been observed. Structural studies suggest electronic effects within the complexes to be strongly affected by steric interactions between the hydrogen atoms of the o-xylyl bridges and the benzimidazole components and their substituents.

Graphical abstract: Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts

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Publication details

The article was received on 30 Apr 2009, accepted on 20 Jul 2009 and first published on 05 Aug 2009


Article type: Paper
DOI: 10.1039/B908613G
Citation: Dalton Trans., 2009,0, 7294-7307
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    Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts

    M. V. Baker, D. H. Brown, P. V. Simpson, B. W. Skelton and A. H. White, Dalton Trans., 2009, 0, 7294
    DOI: 10.1039/B908613G

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