A bimetallic pillared-layer metal–organic coordination framework with a 3D biporous structure†
Abstract
A novel bimetallic [Mn(II)–Fe(III)] 3D biporous pillared-layer metal–organic coordination framework constructed by a cyanometallate anion ([Fe(CN)6]3−) and an organic linker (4,4′-bipy) is found to exhibit permanent porosity with excellent size selective vapour