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Issue 12, 2009
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Two MnII2LnIII4 (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

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Abstract

Two 3d-4f heterometallic compounds of p-tert-butylsulfinylcalix[4]arene were synthesized by the solvothermal method and characterized by some hinged double-dumbbell-like subunits in which two perpendicular dumbbell entities were constructed by an in-between isosceles triangle MnIILnIII2, and two tail-to-tail calixarene molecules, and hinged by the lanthanide–sulfinyl group bonding. The magnetic properties of the title compounds were examined.

Graphical abstract: Two MnII2LnIII4 (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

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Publication details

The article was received on 06 Oct 2008, accepted on 29 Jan 2009 and first published on 17 Feb 2009


Article type: Paper
DOI: 10.1039/B817515B
Citation: Dalton Trans., 2009, 2250-2254
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    Two MnII2LnIII4 (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene

    Y. Bi, X. Wang, B. Wang, W. Liao, X. Wang, H. Zhang, S. Gao and D. Li, Dalton Trans., 2009, 2250
    DOI: 10.1039/B817515B

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