Issue 45, 2008

Ring expansions and contractions of metalloporphyrins

Abstract

Ring expansions or contractions of metalloporphyrins are unusual reactions. In this review, the author will show how the step by step analysis of two serendipitous reactions allows one to unveil their mechanism and to point out the key role of nickel ion in these rearrangements.

Graphical abstract: Ring expansions and contractions of metalloporphyrins

Article information

Article type
Perspective
Submitted
28 Apr 2008
Accepted
29 Jul 2008
First published
09 Oct 2008

Dalton Trans., 2008, 6346-6357

Ring expansions and contractions of metalloporphyrins

H. J. Callot, Dalton Trans., 2008, 6346 DOI: 10.1039/B807066K

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