Issue 24, 2008
From the journal:

Dalton Transactions

Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers†

Bogdan Botar*a  and  Paul Kögerlerab  

* Corresponding authors

a Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, Jülich, Germany
E-mail: b.botar@fz-juelich.de

b Institut für Anorganische Chemie, RWTH Aachen University, Aachen, Germany

Abstract

The effect of acetate concentration on the formation of {SiW10Fe2}-based complexes is demonstrated by the synthesis of an open-shell diiron tungstosilicate derivative featuring two rotational Keggin isomer units.

Graphical abstract: Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

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Article information

DOI
https://doi.org/10.1039/B802147C
Article type
Communication
Submitted
06 Feb 2008
Accepted
21 Apr 2008
First published
07 May 2008

Dalton Trans., 2008, 3150-3152

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Acetate-driven polyoxometalate demetalation: An open-shell diiron polytungstate comprising two rotational Keggin isomers

B. Botar and P. Kögerler, Dalton Trans., 2008, 3150 DOI: 10.1039/B802147C

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