The first stereochemically nonrigid monomeric two-coordinate copper(i) complexes with homoleptic and heteroleptic “N2” donor set†
Abstract
A novel set of stereochemically nonrigid monomeric two-coordinate copper(I) complexes, [Cu(η1-H2CPz″2)2]ClO41, [Cu(HPz″)2]ClO42, and [Cu(HPz″)(η1-H2CPz″2)]ClO43, where Pz″ = 3,5-di-tert-butylpyrazolyl, has been synthesized and characterized by