Effect of metal dilution on the light-induced spin transition in [FexZn1−x(phen)2(NCS)2] (phen = 1,10-phenanthroline)

Abstract

The thermal and light-induced spin transitions in [Fe_xZn_1−x(phen)₂(NCS)₂] (phen = 1,10-phenantholine) have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and undergo the light-induced excited spin state trapping (LIESST) effect at low temperatures. For each compound, the thermal spin transition temperature, T_1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T_1/2 decreases with the metal dilution while T(LIESST) remains unchanged. This behaviour is discussed on the basis of the kinetic study governing the photo-induced back conversion.