Issue 12, 2007

Complexation versusthiadiazole formation for reactions of thiosemicarbazides with copper(ii)

Abstract

The reactions of N,N-substituted thiosemicarbazides with copper salts have been investigated and either copper(II) thiosemicarbazide complexes, 1,3,4-thiadiazolium salts or 1,3,5-thiadiazoles are obtained depending on the Cu(II) salt and solvent used.

Graphical abstract: Complexation versus thiadiazole formation for reactions of thiosemicarbazides with copper(ii)

Supplementary files

Article information

Article type
Communication
Submitted
24 Nov 2006
Accepted
07 Feb 2007
First published
20 Feb 2007

Dalton Trans., 2007, 1194-1196

Complexation versus thiadiazole formation for reactions of thiosemicarbazides with copper(II)

E. López-Torres, A. R. Cowley and J. R. Dilworth, Dalton Trans., 2007, 1194 DOI: 10.1039/B617186A

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