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Issue 7, 2007
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Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate

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Abstract

The synthesis, structure and magnetic properties of [Mn13O8(OEt)6(O2CC6H4OPh)12] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S6 symmetry and an S = 11/2 ground state.

Graphical abstract: Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate

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Publication details

The article was received on 31 Oct 2006, accepted on 07 Dec 2006 and first published on 18 Dec 2006


Article type: Communication
DOI: 10.1039/B615856K
Citation: Dalton Trans., 2007,0, 728-730
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    Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate

    A. Ferguson, K. Thomson, A. Parkin, P. Cooper, C. J. Milios, E. K. Brechin and M. Murrie, Dalton Trans., 2007, 0, 728
    DOI: 10.1039/B615856K

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