Issue 5, 2007
From the journal:

Dalton Transactions

Tetraalkylphosphonium polyoxometalates: electroactive, “task-specific” ionic liquids†

Paul G. Rickert,a   Mark R. Antonio,*a   Millicent A. Firestone,b   Karrie-Ann Kubatko,c   Tomasz Szreder,d   James F. Wishartd  and  Mark L. Dietz*a  

* Corresponding authors

a Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, USA
E-mail: mantonio@anl.gov, mdietz@anl.gov
Fax: +630 252 4225
Tel: +630 252 9267

b Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, USA

c Department of Geological Sciences, University of Miami, Coral Gables, FL, USA

d Department of Chemistry, Brookhaven National Laboratory, Upton, NY, USA

Abstract

The pairing of selected polyoxometalate (POM) anions with appropriate tetraalkylphosphonium cations is shown to yield an original family of ionic liquids, among them an ambient-temperature “liquid POM”.

Graphical abstract: Tetraalkylphosphonium polyoxometalates: electroactive, “task-specific” ionic liquids

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Article information

DOI
https://doi.org/10.1039/B614950M
Article type
Communication
Submitted
13 Oct 2006
Accepted
12 Dec 2006
First published
21 Dec 2006

Dalton Trans., 2007, 529-531

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Tetraalkylphosphonium polyoxometalates: electroactive, “task-specific” ionic liquids

P. G. Rickert, M. R. Antonio, M. A. Firestone, K. Kubatko, T. Szreder, J. F. Wishart and M. L. Dietz, Dalton Trans., 2007, 529 DOI: 10.1039/B614950M

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