Issue 37, 2006

Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As–S anions

Abstract

The synthesis of [(PhAs)2(µ-S2)(µ-S)] and its reactions to form novel Cu(I) complexes are reported, together with a new cleavage reaction of disulfides by Cu(I) thiolates and tertiary phosphines.

Graphical abstract: Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As–S anions

Supplementary files

Article information

Article type
Communication
Submitted
17 Jul 2006
Accepted
24 Aug 2006
First published
31 Aug 2006

Dalton Trans., 2006, 4435-4437

Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As–S anions

R. Langer, W. Shi and A. Rothenberger, Dalton Trans., 2006, 4435 DOI: 10.1039/B610228J

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