Issue 18, 2006

A trinuclear complex containing MnIIMnIIIMnIV, radicals, quinone and chloride ligands potentially relevant to PS II

Abstract

Reaction of MnCl2 with a non-innocent ligand H3L results in an unprecedented mixed-valence trinuclear complex [MnIIMnIIIMnIV(L)(L˙)2(LIQ)Cl] whose structural and magnetic properties are described.

Graphical abstract: A trinuclear complex containing MnIIMnIIIMnIV, radicals, quinone and chloride ligands potentially relevant to PS II

Supplementary files

Article information

Article type
Communication
Submitted
01 Feb 2006
Accepted
10 Mar 2006
First published
23 Mar 2006

Dalton Trans., 2006, 2169-2171

A trinuclear complex containing MnIIMnIIIMnIV, radicals, quinone and chloride ligands potentially relevant to PS II

C. Mukherjee, T. Weyhermüller, K. Wieghardt and P. Chaudhuri, Dalton Trans., 2006, 2169 DOI: 10.1039/B601581F

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