Issue 22, 2005
From the journal:

Dalton Transactions

Novel rhodium and ruthenium carbonyl cluster complexes with face- and edge-bridging GaCp* ligands. Synthesis and structural characterization of the Rh6(CO)12(µ3-GaCp*)4 and Ru6(η6-C)(µ2-CO)(CO)13(µ3-GaCp*)2(µ2-GaCp*) clusters†

Elena V. Grachova,*a   Peter Jutzi,b   Beate Neumannb  and  Hans-Georg Stammlerb  

* Corresponding authors

a Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, Russia
E-mail: bird231102@mail.ru
Fax: +7 812 428 6939
Tel: +7 812 428 4028

b Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, Bielefeld, Germany
E-mail: peter.jutzi@uni-bielefeld.de
Fax: +49 521 106 6026
Tel: +49 521 106 6181

Abstract

Reactions of hexanuclear carbonyl clusters of rhodium Rh6(CO)16 and ruthenium Ru6(η6-C)(µ2-CO)(CO)16 with GaCp* (Cp* = C5Me5) in the mild conditions result in substitution of CO ligands and formation of the Rh6(CO)12(µ3-GaCp*)4 and the Ru6(η6-C)(µ2-CO)(CO)13(µ3-GaCp*)2(µ2-GaCp*) cluster derivatives.

Graphical abstract: Novel rhodium and ruthenium carbonyl cluster complexes with face- and edge-bridging GaCp* ligands. Synthesis and structural characterization of the Rh6(CO)12(µ3-GaCp*)4 and Ru6(η6-C)(µ2-CO)(CO)13(µ3-GaCp*)2(µ2-GaCp*) clusters

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Article information

DOI
https://doi.org/10.1039/B513015H
Article type
Communication
Submitted
13 Sep 2005
Accepted
27 Sep 2005
First published
11 Oct 2005

Dalton Trans., 2005, 3614-3616

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Novel rhodium and ruthenium carbonyl cluster complexes with face- and edge-bridging GaCp* ligands. Synthesis and structural characterization of the Rh6(CO)12(µ3-GaCp*)4 and Ru6(η6-C)(µ2-CO)(CO)13(µ3-GaCp*)2(µ2-GaCp*) clusters

E. V. Grachova, P. Jutzi, B. Neumann and H. Stammler, Dalton Trans., 2005, 3614 DOI: 10.1039/B513015H

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