Issue 18, 2005
From the journal:

Dalton Transactions

α,β-(C–C–C) Agostic bonds in transition metal based olefin metathesis catalyses†

Cherumuttathu H. Suresh*ab  and  Mu-Hyun Baik*a  

* Corresponding authors

a Department of Chemistry and School of Informatics, Indiana University, Bloomington, Indiana, USA

b Division of Computational Modeling and Simulation, Regionnal Research Laboratory (CSIR), Trivandrum, India

Abstract

An α,β-(C–C–C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.

Graphical abstract: α,β-(C–C–C) Agostic bonds in transition metal based olefin metathesis catalyses

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Article information

DOI
https://doi.org/10.1039/B508192K
Article type
Communication
Submitted
09 Jun 2005
Accepted
25 Jul 2005
First published
04 Aug 2005

Dalton Trans., 2005, 2982-2984

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α,β-(C–C–C) Agostic bonds in transition metal based olefin metathesis catalyses

C. H. Suresh and M. Baik, Dalton Trans., 2005, 2982 DOI: 10.1039/B508192K

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