Issue 24, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

Anand I. Bhatt,a   Iain May,*a   Vladimir A. Volkovich,a   Melissa E. Hetherington,b   Bob Lewin,b   Rob C. Thiedb  and  Nigar Ertokc  

* Corresponding authors

a Centre for Radiochemistry Research, Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: Iain.May@man.ac.uk

b Research and Technology, British Nuclear Fuels plc, Sellafield, Seascale, Cumbria, UK

c Ízmir Yüksek Teknoloji Enstitüsü, Fen Fakültesi-Kimya Bölümü, Gülbahçeköyü Urla Izmir, Turkey

Abstract

We report the electrochemical properties of Group 15 quaternary alkyl bistriflimide salts, which have very wide electrochemical windows (between +2.6 and −3.4 V vs. Fc+/Fc for [(Me)4As][N(SO2CF3)2]) when used as supporting electrolytes in MeCN and which can be used for the electrodeposition of very electropositive metals, including Eu, in the molten state.

Graphical abstract: Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B208968H
Article type
Communication
Submitted
17 Sep 2002
Accepted
08 Nov 2002
First published
21 Nov 2002

J. Chem. Soc., Dalton Trans., 2002, 4532-4534

Permissions

Request permissions

Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

A. I. Bhatt, I. May, V. A. Volkovich, M. E. Hetherington, B. Lewin, R. C. Thied and N. Ertok, J. Chem. Soc., Dalton Trans., 2002, 4532 DOI: 10.1039/B208968H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements