Transport of metal salts; encapsulation of anions in dinuclear Cu(II) complexes [Cu2L2SO4]SO4 and [Cu2L2BF4](BF4)3, where L = 2,2’-[1,6-hexanediylbis[(methylimino)methylene]]bis[4-tert-butyl-6-(phenylazomethinyl)phenol]

Paul G. Plieger; Simon Parsons; Andy Parkin; Peter A. Tasker

doi:10.1039/B208062A

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Transport of metal salts; encapsulation of anions in dinuclear Cu(ii) complexes [Cu₂L₂SO₄]SO₄ and [Cu₂L₂BF₄](BF₄)₃, where L = 2,2’-[1,6-hexanediylbis[(methylimino)methylene]]bis[4-tert-butyl-6-(phenylazomethinyl)phenol]

Paul G. Plieger,^a Simon Parsons,^a Andy Parkin^a and Peter A. Tasker*^a

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* Corresponding authors

^a Department of Chemistry, The University of Edinburgh, Joseph Black Building, Kings Buildings, West Mains Road, Edinburgh, UK
E-mail: p.a.tasker@ed.ac.uk

Abstract

Linking salicylaldimine units with a 2,9-diazadecane strap in high yields via a simple Mannich condensation generates a ligand which forms 2 ∶ 2 ∶ 1 assemblies of Cu ∶ L ∶ anion in which the anion is encapsulated in a tetra-cation cavity.

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Supplementary files

Crystal structure data TXT (87K)

Article information

DOI: https://doi.org/10.1039/B208062A
Article type: Communication
Submitted: 16 Aug 2002
Accepted: 19 Sep 2002
First published: 02 Oct 2002

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J. Chem. Soc., Dalton Trans., 2002, 3928-3930

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Transport of metal salts; encapsulation of anions in dinuclear Cu(II) complexes [Cu₂L₂SO₄]SO₄ and [Cu₂L₂BF₄](BF₄)₃, where L = 2,2’-[1,6-hexanediylbis[(methylimino)methylene]]bis[4-tert-butyl-6-(phenylazomethinyl)phenol]

P. G. Plieger, S. Parsons, A. Parkin and P. A. Tasker, J. Chem. Soc., Dalton Trans., 2002, 3928 DOI: 10.1039/B208062A

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Journal of the Chemical Society, Dalton Transactions