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Issue 21, 2002
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The assembly of pentanuclear nickel(II) complexes from asymmetric compartmental ligands and bearing μ3-OH bridges

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Abstract

The asymmetric di-aminic compartmental ligands HL5–HL7 form pentanuclear nickel(II) complexes in which the core is assembled from two dinuclear [Ni2L] units which are each linked to the third Ni atom by bridging μ3-hydroxo groups; the crystal structure of [Ni5(L5)2(OAc)6(OH)2], 1 [HL5 is the proligand 2-{[(2-dimethylaminoethyl)ethylamino]methyl}-6-ethyliminomethyl-4-methylphenol] is reported.

Graphical abstract: The assembly of pentanuclear nickel(ii) complexes from asymmetric compartmental ligands and bearing μ3-OH bridges

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Publication details

The article was received on 05 Aug 2002, accepted on 13 Sep 2002 and first published on 01 Oct 2002


Article type: Communication
DOI: 10.1039/B207631B
Citation: J. Chem. Soc., Dalton Trans., 2002, 3933-3935
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    The assembly of pentanuclear nickel(II) complexes from asymmetric compartmental ligands and bearing μ3-OH bridges

    H. Adams, S. Clunas, D. E. Fenton and D. N. Towers, J. Chem. Soc., Dalton Trans., 2002, 3933
    DOI: 10.1039/B207631B

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