Hydrothermal synthesis and crystal structure of a hybrid material based on [Co4(phen)8(H2O)2(HPO3)2]4+ and a highly reduced polyoxoanion
Abstract
An unusual composite hybrid material [Co4(phen)8(H2O)2(HPO3)2](H3O)3[PMoVI8VIV4O40(VIVO)2] 1 (phen =
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* Corresponding authors
a
Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China
E-mail:
wangenbo@public.cc.jl.cn
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China
c Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, P. R. China
An unusual composite hybrid material [Co4(phen)8(H2O)2(HPO3)2](H3O)3[PMoVI8VIV4O40(VIVO)2] 1 (phen =
M. Yuan, Y. Li, E. Wang, Y. Lu, C. Hu, N. Hu and H. Jia, J. Chem. Soc., Dalton Trans., 2002, 2916 DOI: 10.1039/B203737H
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