Issue 12, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and structural characterisation of the first tris(diacylpnictido)phosphines, P[E{C(O)R}2]3, E = P or As, R = But or Ph

Cameron Jones,*a   Peter C. Junkb  and  Thomas C. Williamsa  

* Corresponding authors

a Department of Chemistry, University of Wales, Cardiff, P.O. Box 912, Park Place, Cardiff, UK

b School of Chemistry, Box 23, Monash University, Clayton, Vic 3800, Australia

Abstract

The reactions of the 2-phospha- or 2-arsa-dionatolithium complexes, [Li(DME){η2-O,O-OC(R)EC(R)}], E = P or As, R = But or Ph, with PCl3 have afforded the first examples of tris(diacylpnictido)phosphines, P[E{C(O)R}2]3, two of which have been structurally characterised.

Graphical abstract: Synthesis and structural characterisation of the first tris(diacylpnictido)phosphines, P[E{C(O)R}2]3, E = P or As, R = But or Ph

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Article information

DOI
https://doi.org/10.1039/B203709M
Article type
Communication
Submitted
16 Apr 2002
Accepted
13 May 2002
First published
23 May 2002

J. Chem. Soc., Dalton Trans., 2002, 2417-2418

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Synthesis and structural characterisation of the first tris(diacylpnictido)phosphines, P[E{C(O)R}2]3, E = P or As, R = But or Ph

C. Jones, P. C. Junk and T. C. Williams, J. Chem. Soc., Dalton Trans., 2002, 2417 DOI: 10.1039/B203709M

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