Supramolecular structure of {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 based on tetrametallic organometallic building blocks constructed from a multitopic tris(pyrazolyl)methaneligand
Abstract
The compound {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 forms a 3D sinusoidal architecture with 16 × 7 Å channels organized by π–π stacking and weak C–H⋯F hydrogen bonds.