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Issue 3, 2002
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Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

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Abstract

The first neutral, tribridged [Rh2]3+ triazenide complex, [(OC)Rh(μ-RNNNR)3Rh(CO)] (R = C6H4Me-p), reacts with NO gas to give the novel nitrosyl [(OC)Rh(μ-RNNNR)3Rh(NO)] with an [Rh2]4+ core linked to NO.

Graphical abstract: Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

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Publication details

The article was received on 31 Oct 2001, accepted on 04 Dec 2001 and first published on 17 Dec 2001


Article type: Communication
DOI: 10.1039/B109972H
Citation: J. Chem. Soc., Dalton Trans., 2002, 305-306
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    Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

    N. G. Connelly, O. D. Hayward, P. Klangsinsirikul and A. G. Orpen, J. Chem. Soc., Dalton Trans., 2002, 305
    DOI: 10.1039/B109972H

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