Issue 3, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Unusual selective substitution of triply bridging carbonylligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(μ3-CO)4 − x(μ3-GaCp*)x(CO)12 clusters, x  = 1–4†

Elena V. Grachova,a   Peter Jutzi,*b   Beate Neumann,b   Lars O. Schebaum,b   Hans-Georg Stammlerb  and  Sergey P. Tunik*a  

* Corresponding authors

a Department of Chemistry, St. Petersburg State University, Universitetskii pr., 2, St. Petersburg, Russia
E-mail: stunik@ST1323.spb.edu

b Fakultät für Chemie, Universität Bielefeld, Bielefeld, Germany
E-mail: peter.jutzi@uni-bielefeld.de

Abstract

Reactions of hexanuclear rhodium clusters with GaCp* (Cp* = C5Me5) result in unusual substitution of face bridging CO ligands to give a series of the Rh6(μ3-CO)4 − x(μ3-GaCp*)x(CO)12 substituted derivatives.

Graphical abstract: Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(μ3-CO)4 − x(μ3-GaCp*)x(CO)12 clusters, x  = 1–4

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Article information

DOI
https://doi.org/10.1039/B109327D
Article type
Communication
Submitted
17 Oct 2001
Accepted
04 Dec 2001
First published
20 Dec 2001

J. Chem. Soc., Dalton Trans., 2002, 302-304

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Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(μ3-CO)4 − x(μ3-GaCp*)x(CO)12 clusters, x  = 1–4

E. V. Grachova, P. Jutzi, B. Neumann, L. O. Schebaum, H. Stammler and S. P. Tunik, J. Chem. Soc., Dalton Trans., 2002, 302 DOI: 10.1039/B109327D

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