Issue 23, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

A dimer-to-dimer metal–metal linear aggregate from a (μ-1,3-NO3)2 double-bridged cis-(2,2′-bipyridine)palladium(ii) cofacial dimer

Shu-Yan Yu,*a   Makoto Fujita*b  and  Kentaro Yamaguchic  

* Corresponding authors

a Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

b Department of Applied Chemistry, School of Engineering, Nagoya University, CREST, Japan Science and Technology Corporation (JST), Chikusa-ku, Nagoya 464-8603, Japan
E-mail: mfujita@apchem.nagoya-u.ac.jp

c Chemical Analysis Center, Chiba University, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Abstract

The first example of a (μ-1,3-NO3)2 double-bridged cofacial dimeric complex of a platinum group metal, {cis-[(2,2′-bipyridine)palladium(II)]2(μ-1,3-NO3)2}(NO3)(PF6)·2CH3CN·2H2O was synthesized by reaction of silver(I) nitrate with cis-(2,2′-bipyridine)palladium(II) chloride in water and by recrystallization with NH4PF6 in acetonitrile; X-ray crystallographic analysis reveals that the cationic dimer is built upon (μ-1,3-NO3)2 double-bridging coordination to the two cis-(2,2′-bipyridine)Pd(II) units in a cofacial arrangement.

Graphical abstract: A dimer-to-dimer metal–metal linear aggregate from a (μ-1,3-NO3)2 double-bridged cis-(2,2′-bipyridine)palladium(ii) cofacial dimer

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B108470B
Article type
Communication
Submitted
18 Sep 2001
Accepted
29 Oct 2001
First published
09 Nov 2001

J. Chem. Soc., Dalton Trans., 2001, 3415-3416

Permissions

Request permissions

A dimer-to-dimer metal–metal linear aggregate from a (μ-1,3-NO3)2 double-bridged cis-(2,2′-bipyridine)palladium(II) cofacial dimer

S. Yu, M. Fujita and K. Yamaguchi, J. Chem. Soc., Dalton Trans., 2001, 3415 DOI: 10.1039/B108470B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements