Issue 13, 2001

A new metal–metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligandN-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2−)

Abstract

The ligand-substitution reaction of Ru2(O2CCH3)4Cl with the tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate dianion (5-Clsalpy2−) led to the unique diruthenium(II,III) compound [{Na(THF)2}{Ru2(O2CCH3)2(5-Clsalpy)2}]·THF (1·THF) which revealed the characteristic 1-D chain structure of the repeating unit [–Na–O–Ru–Ru–O–] and rich redox chemistry.

Graphical abstract: A new metal–metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2−)

Supplementary files

Article information

Article type
Communication
Submitted
10 Apr 2001
Accepted
04 Jun 2001
First published
14 Jun 2001

J. Chem. Soc., Dalton Trans., 2001, 1929-1930

A new metal–metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2−)

H. Miyasaka, C. Kachi-Terajima, T. Ishii and M. Yamashita, J. Chem. Soc., Dalton Trans., 2001, 1929 DOI: 10.1039/B103186B

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