Issue 3, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Geometrical preferences of complexes of terpyridine N-oxideligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide

Angelo J. Amoroso,*a   Miles W. Burrows,a   Anthony A. Dickinson,a   Cameron Jones,a   David J. Willocka  and  Wing-Tak Wongb  

* Corresponding authors

a Department of Chemistry, Cardiff University, PO Box 912, Cardiff, UK
E-mail: amorosoaj@cf.ac.uk

b Department of Chemistry, The University of Hong Kong, Pokfulam Rd, Hong Kong SAR, People’s Republic of China

Abstract

[NiL2][ClO4]2 complexes (L = terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

Graphical abstract: Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide

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Article information

DOI
https://doi.org/10.1039/B008993L
Article type
Communication
Submitted
08 Nov 2000
Accepted
11 Dec 2000
First published
05 Jan 2001

J. Chem. Soc., Dalton Trans., 2001, 225-227

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Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide

A. J. Amoroso, M. W. Burrows, A. A. Dickinson, C. Jones, D. J. Willock and W. Wong, J. Chem. Soc., Dalton Trans., 2001, 225 DOI: 10.1039/B008993L

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