Issue 22, 2000

Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

Abstract

Reaction of (1,4-diisopropyl-1,4,7-triazacyclononane)Li with C5Me4HSiMe2Cl yields the new donor-functionalized ligand, [C5Me4SiMe2(tacn)]H; the alkali-metal salts [C5Me4SiMe2(tacn)]M (M = Li, Na, K) are obtained upon reaction with BuLi, NaN(SiMe3)2 or KN(SiMe3)2.

Supplementary files

Article information

Article type
Communication
Submitted
28 Jun 2000
Accepted
22 Sep 2000
First published
19 Oct 2000

J. Chem. Soc., Dalton Trans., 2000, 4018-4020

Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

G. R. Giesbrecht, A. Gebauer, A. Shafir and J. Arnold, J. Chem. Soc., Dalton Trans., 2000, 4018 DOI: 10.1039/B007075K

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