Issue 13, 1998

Saturated and unsaturated tetraruthenium clusters containing sterically demanding dicyclohexylphosphido ligands: synthesis and structure of [H4Ru4(CO)8(PCy2)4] and [H5Ru4(CO)8(PCy2)3]

Abstract

The thermal reaction of the dinuclear complex [Ru2(CO)4(O2CH)2(PCy2H)2] with molecular hydrogen in cyclohexane afforded the tetranuclear clusters [H4Ru4(CO)8(PCy2)4] (64e) and [H5Ru4(CO)8(PCy2)3] (62e), both of which have a square-planar arrangement of the metal framework.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 2211-2214

Saturated and unsaturated tetraruthenium clusters containing sterically demanding dicyclohexylphosphido ligands: synthesis and structure of [H4Ru4(CO)8(PCy2)4] and [H5Ru4(CO)8(PCy2)3]

G. Süss-Fink, I. Godefroy, A. Béguin, G. Rheinwald, A. Neels, I. G. A. B. G. R. A. N. H. ,. S. and I. G. A. B. G. R. A. N. H. ,. S., J. Chem. Soc., Dalton Trans., 1998, 2211 DOI: 10.1039/A801660G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements