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Issue 13, 1998
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X-Ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

Abstract

A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V–N–O–V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N–O groups.

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Article type: Paper
DOI: 10.1039/A800568K
Citation: J. Chem. Soc., Dalton Trans., 1998,0, 2199-2204
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    X-Ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

    D. Collison, C. David Garner, J. Grigg, C. M. McGrath, J. Frederick W. Mosselmans, E. Pidcock, M. D. Roper, J. M. W. Seddon, E. Sinn, P. A. Tasker, G. Thornton, J. F. Walsh and N. A. Young, J. Chem. Soc., Dalton Trans., 1998, 0, 2199
    DOI: 10.1039/A800568K

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