Issue 8, 1996

Spectroscopic titration of [Re43-H)4(CO)12] with chloride ions. An electron-precise tetranuclear cluster as intermediate in the transformation of a tetranuclear unsaturated cluster into trinuclear unsaturated anions

Abstract

The unsaturated tetrahedral cluster [Re43-H)4(CO)12] easily added halide ions giving [Re4H4X(CO)12] anions, which in the presence of even poor donor species underwent fragmentation to unsaturated triangular cluster anions.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 1771-1773

Spectroscopic titration of [Re43-H)4(CO)12] with chloride ions. An electron-precise tetranuclear cluster as intermediate in the transformation of a tetranuclear unsaturated cluster into trinuclear unsaturated anions

T. Beringhelli, G. D'Alfonso and M. G. Garavaglia, J. Chem. Soc., Dalton Trans., 1996, 1771 DOI: 10.1039/DT9960001771

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