SCHEDULED MAINTENANCE
The reaction of a toluene solution of Ga[GaCl4] with elemental sulfur at ambient temperature gave GaSCl, to which pyridine (py) could be added to yield a crystalline adduct (GaSCl·py)3 featuring a boat-shaped gallium–sulfur ring structure.
J. Ohshita, A. Schier and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 1992, 3561 DOI: 10.1039/DT9920003561
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