Diene and arene compounds of zirconium and hafnium
Abstract
The diene compounds [Hf(η4-CH2CMeCMe
CH2)(PMe3)2Cl2]1, [M(η4-C6H8)(PMe3)2Cl2](M = Zr 2 or Hf 3) and the divalent [Zr(η6-C6H5Me)(PMe3)2Cl2]5 have been prepared. The structure of compound 1 has been determined by low-temperature neutron diffraction (15 K) and the σ2, π nature of the bonding mode of the 2,3-dimethylbutadiene ligand demonstrated from the methylene hydrogen positions. Treatment of 1 with lithium indenide gave [Hf(η5-C9H7)2(η4-CH2
CMeCMe
CH2)]4. The crystal structure of 5 has been determined by X-ray diffraction.