Issue 2, 1985
From the journal:

Journal of the Chemical Society, Dalton Transactions

Nitrosoarene complexes of ruthenium and platinum and their reactions with NO and NO+

Christopher J. Jones,   Jon A. McCieverty  and  Anne S. Rothin  

Abstract

Addition of RNO (R = Ph or o-MeC6H4) to [RuCl(NO)(PPh3)2] afforded the complex [RuCl(NO)(RNO)(PPh3)2] which reacted with I2 to give [RuCll2(NO)(PPh3)2]. The RNO ligand was readily displaced by O2, and treatment with PPh3 or CO caused extensive decomposition without formation of a [graphic omitted] chelate ring. Treatment of [Pt(PhNO)(PPh3)2] with NO+ afforded [Pt{ON(Ph)NO}(PPh3)2]+ isolated as the PF6– salt. The complexes [M{ON(R)NO}(PPh3)2](M = Pt or Pd; R = Ph or p-MeC6H4) were prepared by reaction of [MCl2(PPh3)2] with Ag[ON(R)NO].

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Article information

DOI
https://doi.org/10.1039/DT9850000401
Article type
Paper

J. Chem. Soc., Dalton Trans., 1985, 401-403

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Nitrosoarene complexes of ruthenium and platinum and their reactions with NO and NO+

C. J. Jones, J. A. McCieverty and A. S. Rothin, J. Chem. Soc., Dalton Trans., 1985, 401 DOI: 10.1039/DT9850000401

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