The reaction between [Fe(η-C3H5)(CO)2(NO)] and strong basic phosphine ligands L [PMe3, PEt3, PBun3, or P(C6H11)3] in organic solvents (benzene or diethyl ether) gives the zwitterionic adducts [Fe(η2-CH2 CHCH2PR3)(CO)2(NO)]. The structure has been assigned on the basis of i.r. and n.m.r. spectra and conductivity measurements. The reactivity and the decomposition mechanism are discussed.
Fetching data from CrossRef. This may take some time to load.
Journal of the Chemical Society, Dalton Transactions
- Information Point