Issue 3, 1982
From the journal:

Journal of the Chemical Society, Dalton Transactions

Some oxidative-addition reactions of the diradical, perfluoro-NN′-dimethylethane-1,2-bis(amino-oxyl), CF3N(O)CF2CF2N(O)CF3, with iridium(I) and platinum(0) complexes

Brian L. Booth,   Robert N. Haszeldine  and  Robert G. G. Holmes  

Abstract

The stable diradical CF3N(O)CF2CF2N(O)CF3 reacts with trans-[IrCl(CO)L2](L = PPh3, AsPh3, or PMePh2), trans-[Ir{ON(CF3)2}(CO)(PPh3)2], and [Pt(PPh3)4] to form the seven-membered ring metallacyclic complexes [[graphic omitted]Cl(CO)L2], [[graphic omitted]{ON(CF3)2}(CO)(PPh3)2], and [[graphic omitted](PPh3)2] respectively.

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Article information

DOI
https://doi.org/10.1039/DT9820000671
Article type
Paper

J. Chem. Soc., Dalton Trans., 1982, 671-672

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Some oxidative-addition reactions of the diradical, perfluoro-NN′-dimethylethane-1,2-bis(amino-oxyl), CF3N(O)CF2CF2N(O)CF3, with iridium(I) and platinum(0) complexes

B. L. Booth, R. N. Haszeldine and R. G. G. Holmes, J. Chem. Soc., Dalton Trans., 1982, 671 DOI: 10.1039/DT9820000671

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