Issue 20, 1973

Weak complexes of sulphur and selenium. Part II. Complex species of SO2, SOCl2, and SO2Cl2 with the thiocyanate ligand

Abstract

The formation of 1 : 1 complex species between SO2, SOCl2, and SO2Cl2 with the SCN ligand is reported in dilute solutions. Their thermodynamic constants point to a weak association of a charge-transfer type. The nature of the complex species is discussed in relation to polarisability and basicity of the SCN ligand.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 2148-2150

Weak complexes of sulphur and selenium. Part II. Complex species of SO2, SOCl2, and SO2Cl2 with the thiocyanate ligand

S. Wasif and S. B. Salama, J. Chem. Soc., Dalton Trans., 1973, 2148 DOI: 10.1039/DT9730002148

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