The signs of the quadrupole coupling constants are positive for cis-SnCl4,2MeCN, trans-SnCl4,2PEt3, and trans-SnCl4,2AsEt3 and this is consistent with the order of bond polarity Sn–N (sp-hybridized) > Sn–Cl > Sn–P or Sn–As.
D. Cunningham and M. J. Frazer, J. Chem. Soc., Dalton Trans., 1972, 1647 DOI: 10.1039/DT9720001647
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