Issue 24, 2017

Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

Abstract

Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.

Graphical abstract: Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2017
Accepted
01 Nov 2017
First published
01 Nov 2017
This article is Open Access
Creative Commons BY-NC license

Catal. Sci. Technol., 2017,7, 5843-5846

Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

R. M. Islamova, M. V. Dobrynin, A. V. Vlasov, A. A. Eremina, M. A. Kinzhalov, I. E. Kolesnikov, A. A. Zolotarev, E. A. Masloborodova and K. V. Luzyanin, Catal. Sci. Technol., 2017, 7, 5843 DOI: 10.1039/C7CY02013A

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