Issue 12, 2017
From the journal:

Catalysis Science & Technology

Room temperature silylation of alcohols catalyzed by metal organic frameworks†

Amarajothi Dhakshinamoorthy, ORCID logo *ab   Andrea Santiago-Portillo, ORCID logo b   Patricia Concepción, ORCID logo b   José R. Herance,c   Sergio Navalón, ORCID logo b   Mercedes Alvaro ORCID logo b  and  Hermenegildo Garcia ORCID logo *bd  

* Corresponding authors

a School of Chemistry, Madurai Kamaraj University, Tamil Nadu, 625 021 India
E-mail: admguru@gmail.com

b Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politècnica de València, Av. De los Naranjos s/n, Valencia, Spain
E-mail: hgarcia@qim.upv.es

c Grupo de Imagen Médica Molecular, Vall d'Hebron Research Institute, CIBBIM-Nanomedicine, Pg. Vall d'Hebron 119-129, Barcelona, Spain

d Centre of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia

Abstract

The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction conditions as evidenced by powder XRD and can be reused with minimal activity decrease.

Graphical abstract: Room temperature silylation of alcohols catalyzed by metal organic frameworks

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Article information

DOI
https://doi.org/10.1039/C7CY00834A
Article type
Communication
Submitted
27 Apr 2017
Accepted
23 May 2017
First published
24 May 2017

Catal. Sci. Technol., 2017,7, 2445-2449

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Room temperature silylation of alcohols catalyzed by metal organic frameworks

A. Dhakshinamoorthy, A. Santiago-Portillo, P. Concepción, J. R. Herance, S. Navalón, M. Alvaro and H. Garcia, Catal. Sci. Technol., 2017, 7, 2445 DOI: 10.1039/C7CY00834A

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