Issue 2, 2017

Recent advances in the textural characterization of hierarchically structured nanoporous materials

Abstract

This review focuses on important aspects of applying physisorption for the pore structural characterization of hierarchical materials such as mesoporous zeolites. During the last decades major advances in understanding the adsorption and phase behavior of fluids confined in ordered nanoporous materials have been made, which led to major progress in the physisorption characterization methodology (summarized in the 2015 IUPAC report on physisorption characterization). Here we discuss progress and challenges for the physisorption characterization of nanoporous solids exhibiting various levels of porosity from micro- to macropores. While physisorption allows one to assess micro- and mesopores, a widely employed method for textural analysis of macroporous materials is mercury porosimetry and we also review important insights associated with the underlying mechanisms governing mercury intrusion/extrusion experiments. Hence, although the main focus of this review is on physical adsorption, we strongly emphasize the importance of combining advanced physical adsorption with other complementary experimental techniques for obtaining a reliable and comprehensive understanding of the texture of hierarchically structured materials.

Graphical abstract: Recent advances in the textural characterization of hierarchically structured nanoporous materials

Article information

Article type
Review Article
Submitted
19 May 2016
First published
19 Oct 2016

Chem. Soc. Rev., 2017,46, 389-414

Recent advances in the textural characterization of hierarchically structured nanoporous materials

K. A. Cychosz, R. Guillet-Nicolas, J. García-Martínez and M. Thommes, Chem. Soc. Rev., 2017, 46, 389 DOI: 10.1039/C6CS00391E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements