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Issue 24, 2013
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Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers

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Abstract

Cucurbit[n]urils are a family of molecular container hosts bearing a rigid hydrophobic cavity and two identical carbonyl fringed portals. They have attracted much attention in supramolecular chemistry because of their superior molecular recognition properties in aqueous media. This review highlights the recent advances and challenges in the field of cucurbit[n]uril-based coordination chemistry. It not only presents progress in the knowledge of such macrocyclic compounds, which range from simple to complicated architectures, but also presents new routes of synthesis and their advantages in hybrid porous solids. The concept of structure “inducer” for their structural design to achieve predictable structures and controlled pores is described. The large pore sizes and hydrophobic cavities of these compounds that lead to unprecedented properties and potential applications are also discussed.

Graphical abstract: Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers

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Publication details

The article was received on 18 Jul 2013 and first published on 18 Sep 2013


Article type: Review Article
DOI: 10.1039/C3CS60261C
Citation: Chem. Soc. Rev., 2013,42, 9480-9508
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    Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers

    X. Ni, X. Xiao, H. Cong, L. Liang, K. Cheng, X. Cheng, N. Ji, Q. Zhu, S. Xue and Z. Tao, Chem. Soc. Rev., 2013, 42, 9480
    DOI: 10.1039/C3CS60261C

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