Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 2, 1999
Previous Article Next Article

Reducing the NMR line widths of quadrupole nuclei by employing supercritical solvents

Abstract

An outline of the use of supercritical solvents in NMR spectroscopy is given, with emphasis on instrumentation and applications. Especially the advantages of the low viscosity of supercritical solvents, resulting in appreciable reductions of the line widths of NMR resonances of quadrupole nuclei (I > 1/2), are discussed. The main focus of the review is on the development of transition metal and 14N NMR spectroscopy, to aid the analysis of transition metal complexes. The choices of the supercritical solvent and ligand modifications are discussed in the context of solubility and reduction of the line width.

Back to tab navigation
Please wait while Download options loads

Article type: Paper
DOI: 10.1039/A800941D
Citation: Chem. Soc. Rev., 1999,28, 135-141
  •   Request permissions

    Reducing the NMR line widths of quadrupole nuclei by employing supercritical solvents

    S. Gaemers and C. J. Elsevier, Chem. Soc. Rev., 1999, 28, 135
    DOI: 10.1039/A800941D

Search articles by author