Issue 10, 2017
From the journal:

Physical Chemistry Chemical Physics

Nonstoichiometric copper chalcogenides for photo-activated alkyne/azide cycloaddition†

Hong Yan Zou, ORCID logo ‡a   Ming Xuan Gao,‡b   Tong Yang,a   Qiao Ling Zeng,a   Xiao Xi Yang,a   Feng Liu,c   Mark T. Swihart,*d   Na Li ORCID logo *c  and  Cheng Zhi Huang ORCID logo *ab  

* Corresponding authors

a Key Laboratory of Luminescence and Real-Time Analytical Chemistry (Southwest University), Ministry of Education, College of Pharmaceutical Science, Southwest University, Chongqing, China
E-mail: chengzhi@swu.edu.cn

b College of Chemistry and Chemical Engineering, Southwest University C, Chongqing, China

c Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: lina@pku.edu.cn

d Department of Chemical and Biological Engineering, University at Buffalo (SUNY), Buffalo, NY 14260-4200, USA
E-mail: swihart@buffalo.edu

Abstract

Nonstoichiometric copper chalcogenides with heavy copper vacancies can be used as an effective photo-activated catalyst for the Huisgen [3+2] cycloaddition reaction as Cu(I) can be released corresponding to holes (Cu-defects) under light irradiation. These strategies expand new possibilities for carrying out prototypical click chemistry in the presence of functional groups.

Graphical abstract: Nonstoichiometric copper chalcogenides for photo-activated alkyne/azide cycloaddition

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Article information

DOI
https://doi.org/10.1039/C7CP00724H
Article type
Communication
Submitted
02 Feb 2017
Accepted
22 Feb 2017
First published
22 Feb 2017

Phys. Chem. Chem. Phys., 2017,19, 6964-6968

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Nonstoichiometric copper chalcogenides for photo-activated alkyne/azide cycloaddition

H. Y. Zou, M. X. Gao, T. Yang, Q. L. Zeng, X. X. Yang, F. Liu, M. T. Swihart, N. Li and C. Z. Huang, Phys. Chem. Chem. Phys., 2017, 19, 6964 DOI: 10.1039/C7CP00724H

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