Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization

Weiyu Wang; Jun Xu; Yanxi Zhao; Guodong Qi; Qiang Wang; Chao Wang; Jinlin Li; Feng Deng

doi:10.1039/C7CP00352H

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Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization†

Weiyu Wang,^a Jun Xu,*^a Yanxi Zhao,^b Guodong Qi,^a Qiang Wang,^a Chao Wang,^a Jinlin Li^b and Feng Deng

*^a

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^a National Center for Magnetic Resonance in Wuhan, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China
E-mail: xujun@wipm.ac.cn, dengf@wipm.ac.cn

^b Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan 430074, China

Abstract

We demonstrated the facet dependence of pairwise addition of hydrogen in heterogeneous catalysis over Pd nanocrystal catalysts via NMR using para-hydrogen-induced polarization.

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DOI: https://doi.org/10.1039/C7CP00352H
Article type: Communication
Submitted: 17 Jan 2017
Accepted: 19 Jan 2017
First published: 19 Jan 2017

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Phys. Chem. Chem. Phys., 2017,19, 9349-9353

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Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization

W. Wang, J. Xu, Y. Zhao, G. Qi, Q. Wang, C. Wang, J. Li and F. Deng, Phys. Chem. Chem. Phys., 2017, 19, 9349 DOI: 10.1039/C7CP00352H

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Physical Chemistry Chemical Physics

Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization†

Abstract

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Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization

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