Issue 2, 2017
From the journal:

Physical Chemistry Chemical Physics

Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces†

M. Dunwell,a   Junhua Wang,a   Y. Yan*a  and  B. Xu*a  

* Corresponding authors

a Department of Chemical and Biomolecular Engineering, Center for Catalytic Science and Technology, University of Delaware, Newark, DE 19716, USA
E-mail: yanys@udel.edu, bxu@udel.edu

Abstract

The adsorption of alkali and tetraalkylammonium cations on Pt is investigated using surface enhanced infrared absorption spectroscopy and carbon monoxide as a probe molecule. Alkali cations exhibit a stronger adsorption than organic cations, with potassium showing the strongest effect, followed by sodium and lithium.

Graphical abstract: Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces

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Article information

DOI
https://doi.org/10.1039/C6CP07207K
Article type
Communication
Submitted
20 Oct 2016
Accepted
08 Dec 2016
First published
08 Dec 2016

Phys. Chem. Chem. Phys., 2017,19, 971-975

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Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces

M. Dunwell, J. Wang, Y. Yan and B. Xu, Phys. Chem. Chem. Phys., 2017, 19, 971 DOI: 10.1039/C6CP07207K

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