Programmable diode/resistor-like behavior of nanostructured vanadium pentoxide xerogel thin film

Abstract

Electrical properties of a Cr/V₂O₅/Cr structure are investigated and switching of the device due to electrochemical reactions is observed at low bias (<1 V). Depending on the polarity of the first applied bias, the switched device can behave like a diode (forward sweep first) or a resistor (reverse sweep first). The switching is irreversible and persistent, lasting for more than one month. By performing environmental tests, we prove that water molecules in the atmosphere and intercalated in the xerogel film are involved in the electrochemical reactions. It is proposed that an interfacial layer with reduced oxidation state forms at the Cr/V₂O₅ interface, and creates a higher Schottky barrier due to rise of electron affinity. Different interfacial layer thicknesses in forward and reverse first sweeps are responsible for different I–V characteristics in subsequent sweeps. The results suggest future applications of these V₂O₅ thin films in low-power read-only memory devices and diode-resistor networks.