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Issue 26, 2015
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A new two-dimensional metal–organic framework with high spin-filtering efficiency

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Abstract

Here we propose a family of two-dimensional organometallic lattices based on first principle calculations. The proposed lattice is designed by assembling molecular building blocks of a naphthalene molecule functionalized by –NH groups and transition metals which are surrounded by four –NH moieties, creating a square planar geometry. The predicted organometallic lattices (with Fe, Cr and Co) are shown to exhibit half metallicity and therefore this class of materials has great promise for application of spintronics.

Graphical abstract: A new two-dimensional metal–organic framework with high spin-filtering efficiency

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Publication details

The article was received on 08 Mar 2015, accepted on 28 May 2015 and first published on 08 Jun 2015


Article type: Paper
DOI: 10.1039/C5CP01359C
Author version available: Download Author version (PDF)
Citation: Phys. Chem. Chem. Phys., 2015,17, 17437-17444
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    A new two-dimensional metal–organic framework with high spin-filtering efficiency

    B. Mandal and P. Sarkar, Phys. Chem. Chem. Phys., 2015, 17, 17437
    DOI: 10.1039/C5CP01359C

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