The visible transmittance and solar modulation ability of VO2 flexible foils simultaneously improved by Ti doping: an optimization and first principle study

Abstract

The Mott phase transition compound vanadium dioxide (VO₂) shows promise as a thermochromic smart material for the improvement of energy efficiency and comfort in a number of applications. However, the use of VO₂ has been restricted by its low visible transmittance (T_vis) and limited solar modulation ability (ΔT_sol). Many efforts have been made to improve both of these limitations, but progress towards the optimization of one aspect has always come at the expense of the other. This paper reports that Ti doping results in the improvement of both the T_vis and ΔT_sol of VO₂-nanoparticle-derived flexible foils to the best levels yet reported. Compared with an undoped VO₂ foil, a 15% increase (from 46.1% to 53%) in T_vis and a 28% increase (from 13.4% to 17.2%) in ΔT_sol are achieved at a Ti doping level of 1.1%, representing the best performance reported for similar foils or films prepared using various methods. Only a defined doping level of less than 3% is beneficial for simultaneous improvement in T_vis and ΔT_sol. First principle calculations suggest that an increase in the intrinsic band gap of VO₂ (M) and the reduced electron density at Fermi level of VO₂ (R) cooperate to result in the improvement of ΔT_sol and that an enhancement in the optical band gap of VO₂ (M) leads to the increase of T_vis.