Issue 17, 2013

Heterogeneous vibrational relaxation of carbon monoxide

Abstract

The first results relating to heterogeneous vibrational relaxation of carbon monoxide in an Al2O3 ceramics tube are reported, together with an estimation of its probability. It was found that the probability of heterogeneous relaxation εv of the first-excited state of CO on the Al2O3 surface lies in the range (5 to 7) × 10−2. The measurements show that the probabilities of heterogeneous relaxation of CO(X1Σ, v) do not depend on the value of v, at least for v = 1, 2 and 3.

Graphical abstract: Heterogeneous vibrational relaxation of carbon monoxide

Article information

Article type
Paper
Submitted
05 Jan 2013
Accepted
27 Feb 2013
First published
01 Mar 2013

Phys. Chem. Chem. Phys., 2013,15, 6215-6218

Heterogeneous vibrational relaxation of carbon monoxide

G. M. Grigorian and A. Cenian, Phys. Chem. Chem. Phys., 2013, 15, 6215 DOI: 10.1039/C3CP00040K

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